This article was originally published in the January/February 1998 issue of Home Energy Magazine. Some formatting inconsistencies may be evident in older archive content.
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Home Energy Magazine Online January/February 1998
Black Stains in Houses: Soot, Dust, or Ghosts?
by Frank Vigil
Builders are never more surprised than when they walk into one of their newly built model homes and find black stains at wall-to-floor joints and on previously pristine carpeting underneath doorways. What causes these stains and how can builders and homeowners prevent them?
The most recent and increasingly common form of staining is caused not by dirt or dust but by soot (see Dirt and Dust Also Cause Ghosting Stains). Ghosting from soot is seen primarily in more recent construction, but diagnosticians have detected soot stains in older residences as well. Typically, newer homes--often still under warranty--are the focus of attention. There have even been reports of the problem in newly built, still unoccupied, model homes. Unfortunately, there are as many opinions about the causes of ghosting as there are occurrences of the mystery.
The black soot will outline items, such as ornaments and pictures hanging on walls. Some of the substances seem to have a particular affinity for plastics, such as coffeemakers, blenders, or garbage cans. Deposits have also frequently been observed along the traceline between carpeted flooring and the edge of draperies, vertical blinds and bed ruffles--even on the inside of refrigerators! The marks may be random smears or they may form clear geometric patterns, following the lines of the framing behind the surface. The marks range in size from small and isolated spots to soot running along the entire height of a wall.
Although there have been isolated occurrences during the past decade, reports of this problem have increased significantly during the past few years. However, no conclusive causes or solutions have been determined.
Observers typically claim that the deposits are a result of (depending upon geographic location) fireplace problems or mold caused by condensation on cold surfaces. Few builders understand house-as-a-system interactions, and most seek a single source to blame for the problem. In fact, there are always two culprits at fault. Any time deposition of soot, dust, or carbon appears, first there must be a source of the material, and second, there must be a driving force to cause the material to deposit itself on a surface.Sources of the Soot Investigations in buildings across the nation reveal multiple sources of the stains. Lab analyses indicate ingredients ranging from carbon soot (that might come from fireplaces, water heaters, furnaces, standing pilot lights, candles, cigarette smoke, cooking byproducts, and even automobile exhaust) to other ingredients such as paraffin, benzene, toluene, silicates, iron oxide, cellulose and cotton, dirt or clay, pollen and carbonates (typically found in airborne dust), common grease, and nicotine. One lab even reported that these black deposits could be the result of carbon from automobile tires which becomes airborne as tires become road-worn (although the authors were unable to substantiate this information). Occasionally, tests do indicate mold spores and/or mildew, but these are easily identified and should not be confused with the increasingly more common forms of black stains that are cropping up.
Carbon molecules act in ways that can make precise identification difficult. Although the black color often leads to the assumption that the sole ingredient of the material is from a combustion-related source, we have learned that this is not always the case.
Hydrocarbon compounds will seek equilibrium with the surrounding environment (Frick's law). That is, they will absorb whatever is in the surrounding air. As the concentration of pollutants increases or decreases, the concentration in the carbon molecules will change. The length of time required for this to occur depends on many different factors, ranging from ambient temperature and molecular weight of the particles to the polarity of the compounds involved. Although laboratory analysis can tell us if the sample contains carbon soot commonly found from incomplete combustion, it cannot positively identify the actual source of the material.Driving Forces Once the sources are identified, a diagnostician must determine what driving forces are responsible for depositing the material. This often requires some real detective work.
There are three known forces at work that can be responsible for the deposits. They are impaction (forced air), gravity, and attraction (electrostatic forces and moisture). The location of the deposits gives a good indication of which of the three forces may be responsible.
Dark stains on carpet underneath a bedroom door, for example, are an indication that the door is probably often closed. Supply air coming from registers located inside the bedroom pressurizes the room. Air in high-pressure areas like the newly pressurized bedroom automatically seeks low-pressure areas. So the air in the positively pressurized bedroom will seek the path of least resistance toward the lowest pressure. This lowest pressure area would be the main body of the house where the cold air return is located. Air passes underneath the closed door, causing the carpet to act as a filter for the air. Over time, the carpeting will pick up enough airborne particles to cause the discoloration. This phenomenon--probably one of the more common ones observed--is an example of impaction or forced air.
Gravity is usually far easier to establish than the other two types of driving forces. Thanks to a study by John Spengler of the Harvard School of Public Health, we know how long particles of different sizes can remain airborne. According to Spengler, human hair, skin flakes, observable dust in air, and common pollens, all ranging in diameter from less than 10 microns (dust) to 150 microns (human hair), require approximately five seconds to settle 1 m (3.2 ft). Mite allergens, common spores, and bacteria, ranging in size from 1 micron (bacteria) to 20 microns (common spores) require five minutes to settle 1 m. Particles such as cat dander, tobacco smoke, metal and organic fumes, and cell debris, all ranging in size from 0.01 microns (cell debris) to 0.9 microns (cat dander), require a full ten hours to settle 1 m. On the far side, viruses, smaller than 0.01 micron, will remain airborne for as long as 10 days before settling 1 m. Soot, which is carbon black particulate, ranges in size from 0.03 to 3 microns, and can remain airborne for prolonged periods of time before settling.
Thanks to gravity, all debris eventually settles (assuming there's no wind, stack air, or forced air to keep it airborne). Settled particles tend to cover most flat surfaces in a house in a rather uniform manner. However, other driving forces, such as impaction (forced air) might be at work as well, bringing the particles into the building where gravity then begins its work. For example, a duct system, with a leaky return located in the garage, will act like a household vacuum, sucking up auto exhaust fumes and other airborne contaminants floating about. The house, unfortunately, becomes the vacuum bag, and is the repository for everything sucked in by the return. And guess who lives inside the vacuum bag, serving as the final filtering system? You.
Even if return ducts are tight or are not located in the garage, leaky supply ducts located anywhere outside the heated space can make the house have a negative pressure with respect to the outside. This negative pressure then causes outside air, along with whatever is in that air to enter the house through cracks, crevices, and holes. Once inside, the particulate in the air will either randomly settle on various flat surfaces (gravity) or follow the airstream until it strikes a solid surface (impaction). Leaky interior walls, open to the attic, may show discoloration at the wall-to-floor connection where carpeting has been filtering the air as it passes up into the wall.
Recent research by J. David Krause of Pure Air Control Services and Kaiss K. Al-Ahmady at the Florida Department of Health, Bureau of Environmental Toxicology, has focused on how particles, when properly charged, will coat a surface that has an opposite charge.
Air coming out of the air handler (central heating/air conditioning system) at a high enough velocity, and then passing through a lined duct system, such as duct board, can become electrically charged. The ACCA's Manual D for residential duct systems, suggests a velocity of between 600 and 900 feet per minute (FPM) for trunk ducts (as opposed to duct branches), depending on the type of duct system (rigid or flex) and whether it is the supply side or the return side. Measured velocity in many of the houses with soot deposition problems has been as high as 4,000 FPM, with typical numbers in the 1,500-2,000 FPM range. Also, the relative humidity in these houses has been lower than 55%, and there is a source of carbon soot (if nothing else, at least a candle burning).
This charge is then passed on to any particles moving through the airstream. In a duct system that has both high velocity and some portion of the system lined with fiberglass, two kinds of charging can occur. First, particles that are simply passed along the fiberglass surface at high speed may receive a unipolar charge. Once charged, the particles will be naturally attracted to any surface in the home that has the opposite charge. The second charging condition is called bipolar; it occurs when the particulate is caught in some air turbulence within the duct system. Due to the complex electrical process that this situation causes, the particles have both a positive and a negative charge. Thus, the particles are now attracted to each other, and collect to form larger, more visible particles. This substance will then either attach itself to a charged surface in the house, settle onto a flat surface, or deposit as a result of impaction--on fan blades, for example, or on the filter media for the air handler.Not-So-Mysterious Ghostly Marks Researchers have observed that staining happens more frequently during the winter months, but it also occurs during summer months when interior relative humidity is below 50%. The source for the soot varies. Soot staining has been found in houses where owners didn't burn candles and the only source of combustion was a standing pilot light in a gas log fireplace. Other examples include homes where gas log fireplace logs were adjusted (more were added), causing increased interference with the flames and resulting in significantly large quantities of carbon soot production. The house was literally coated with soot stains.
One homeowner in Texas has been frequently burning up to 10 candles at a time for more than 12 years in the same house with no problems--until now. Last year, she went to a well-known clothing store that also carries various decorator items. The store was promoting a very soft, aromatic wax candle. The homeowner replaced all of her existing candles with these new ones, and that's when the problems started. Stains began to appear after several months. Soon, stains appeared on walls, windows, fabrics (drapes, upholstery, clothing, etc.), and electronic equipment. Within a few more months, the stains were obvious on most everything else in the house, including plastic items, electrical outlets, light and fan fixtures and even in the refrigerator. This is a classic case of soot plating caused by candles. Laboratory tests of the candles indicated that they produced exceptionally high levels of soot (some candles burn dirtier than others). (Because of ongoing litigation, further information about this situation is being kept under wraps.)
Another homeowner was fanatical about cleaning her house. When she began to find dust stains, she thought she must have been doing a poor job of vacuuming. When she finally called us at Advanced Energy for an analysis, we discovered that her vacuum cleaner was the actual source of the problem! Vacuums often leak more dust back to the house than they remove.
In another case, Advanced Energy was called to investigate a problem house where all of the carpeting had been replaced twice, as a result of mysterious black lines that appear every 4 ft on our upstairs carpeting. Diagnostics, including pressure mapping of the house, revealed the source of the problem. The two-story house was served by a single air handler, located in the garage. Anyone familiar with construction knows that underneath the carpet, the subfloor usually consists of 4-ft x 8-ft sheets of plywood. The ductwork for the upstairs was located in the floor volume, between the first and second floors. One other clue for this problem was the Volvo with a diesel engine parked in the garage. The return duct connection to the air handler was very leaky, as were all of the supply ducts. When the homeowner warmed the car up each morning, the return duct sucked the exhaust from the car, and the soot then leaked into the floor volume from the supply leaks. The pressurized floor volume then pushed the air--and all that was in it--up through the seams in the plywood sheets making up the subfloor. The carpet served as the filter for this air.Cleaning Up the Mess Unfortunately, we don't have all the answers yet. We still have much to learn about the interactions among the various forces and pollutants involved in ghosting. What combinations of relative humidity, air velocity, and source pollutants are necessary to create a problem? How long must these factors be present before a problem is apparent? What factors might exist that we don't yet know about?
We do know enough, at least, to be able to begin taking positive action (see The Ghosting Investigator's Checklist). We know that houses work as systems. We know how to deal with driving forces by ensuring that the pressure and thermal boundaries of our houses are aligned. We know that houses should be tight and well sealed at the top, including wall-to-attic connections. We know that the air handler and ductwork function as an integrated system within the house system, and that they should be designed to complement one another and installed to meet recommended industry standards. We know that houses should be pressure balanced when the air handler and exhaust fan are in use and interior doors are closed. We know that insulation should be installed without compression and voids to avoid cold interior surfaces. On top of all of this, we know that houses should be performance tested to ensure that all recommendations and specifications are met. Finally, we know that homeowners--as well as builders and trade allies--must be educated on house-as-a-system issues and the consequences of various actions.
Frank Vigil is a building science specialist at Advanced Energy Corporation in Raleigh, North Carolina.
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